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Home > Surface Modification > Aminoalkanethiol >
11-Amino-1-undecanethiol, hydrochloride
*Estimated. Exact shipping date will be notified.
For Research Use Only Products
Application: SAM preparation, amine group coating
Chemical Description: 11-Amino-1-undecanethiol, hydrochloride CAS: 143339-58-6
Appearance: White or slightly reddish white crystalline powder Purity: ≥90.0% (HPLC, derivatization) MW: 239.85, C11H26ClNS
Storage Condition: -20ºC, protect from light and metal Shipping Condition: ambient temperature Structural FormulaAminoalkanethiols
are utilized for the modification of a gold surface to introduce amino
groups on the surface. Dojindo’s newly developed
16-Amino-1-hexadecanethiol has a 16-carbon chain, which is the longest
alkanethiol available in the market. It is expected that
16-Amino-1-hexadecanethiolwill form the most stable SAM on a gold
surface among the aminoalkanethiol compounds because of the greater
Van-der-Waals force between alkane groups. Five different
aminoalkanethiols including Amino-EG6-undecanethiol, hydrochloride are
available for gold surface modification. Amino-EG6-undecanethiol
is used for hydrophilic surface preparation. The amino group is usually
modified using aminereactivematerials, such as proteins or
biomaterials, to functionalize the gold surface. Several researchers
have reported SAMs of short alkylchain aminoalkanethiols, and there are
an increasing number of reports of long alkyl chain compounds. Takahara
and others formed a monolayer of 11-Amino-1-undecanethiol on a gold
electrode and studied the effect of the terminal groups on the redox
responses of ferrocene derivatives using the voltammetric method. They
also reported the relationship between the alkyl chain length of
aminoalkanethiols and the redox behavior of
2,3-dichloro-1,4-naphtoquinone attached to the terminal amino group.
Tanahashi and coworkers modified a gold surface with SAMs of several
kinds of functionalized alkanethiols. They reported the effect of their
terminal functional groups on apatite formation in a simulated body
fluid using X-ray photoelectron spectroscopic (XPS) measurement and
quartz crystal microbalance (QCM) method.
References 1. J. M. Brockman, A. G. Frutos and R. M. Corn, A Multistep Chemical Modification Procedure To Create DNA Arrays on Gold Surface for the Study of Protein-DNA Interactions with Surface Plasmon Resonance Imaging, J. Am. Chem. Soc., 1999, 121, 8044. 2. Y. Yoshimi, T. Matsuda, Y. Itoh, F. Ogata and T. Katsube, Surface Modifications of Functional Electrodes of a Light Addressable Potentiometric Sensor (LAPS): Non-Dependency of pH Sensitivity on the Surface Functional Group, Mater. Sci. Eng. C, 1997, 5, 131. 3. M. Tanahashi and T. Matsuda, Surface Functional Group Dependence on Apatite Formation on Self-assembled Monolayers in a Simulated Body Fluid, J. Biomed. Mater. Res., 1997, 34, 305. 4. J. Tien, A. Terfort and G. M. Whitesides, Microfaburication through Electrostatic Self-Assembly, Langmuir, 1997, 13, 5349. 5. F. Mukae, H. Takemura and K. Takehara, Electrochemical Behavior of the Naphtoquinone Anchored onto a Gold Electrode through the Self-Assembled monolayers of Aminoalkanethiol, Bull. Chem. Soc. Jpn., 1996, 69, 2461. 6. S. Rubin, G. Bar, R. W. Cutts, J. T. Chow, J. P. Ferraris, and T. A. Zawodzinski, Electrical Communication Between Glucose Oxidase and Different Ferrocenylalkanethiol Chain Lengths, Mater. Res. Soc. Symp. Proc., 1996, 413, 377. 7. K. Takehara and H. Takemura, Electrochemical Behaviors of Ferrocene Derivatives at an Electrode Modified with Terminally Substituted Alkanethiol Monolayer Assemblies, Bull. Chem. Soc. Jpn., 1995, 68, 1289. 8. K. Takehara, H. Takemura and Y. Ide, Electrochemical Studies of the Terminally Substituted Alkanethiol Monolayers Formed on a Gold Electrode; Effect of the Terminal Group on the Redox Responses of Fe(CN)63-,Ru(NH3)63+ and Ferrocenedimethanol, Electrochim. Acta, 1994, 39, 817. 9. H. J. Lee, A. W. Wark, Y. Li and R. M. Corn, Fabricating RNA Microarrays with RNA-DNA Surface Ligation Chemistry, Anal. Chem., 2005, 77, 7832.
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All Products are applicable only for life science research. Not for diagnostic research use. Prices listed are for U.S. customer only and may vary in other countries.
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